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Geologica Carpathica, 2026, vol. 77, no. 1 in press
Petrology and geochemistry of hydrothermal alteration types at the Elatsite porphyry-copper deposit (Bulgaria)
Abstract
The formation of the Elatsite deposit is related to the emplacement of several Upper Cretaceous porphyritic intrusions with the most significant intrusions of quartz-monzodiorite and granodiorite porphyries. The surface exposure of the Elatsite deposit provides an opportunity for investigating the lithogeochemical features of different hydrothermal alteration types. Petrographic observation combined with detailed geochemical analysis of the hydrothermal alteration types and chemical features of secondary biotite, amphibole, plagioclase and chlorite, led to the assessment of gains and losses of major, trace and REE elements and the origin of fluids for the variety of alterations. The Na–Ca alteration is probably formed from a mixture of magmatic and external fluids. The Na–Ca–K-silicate alteration is formed during fluid–fluid interaction of magmatic and external fluid, with predominance of the magmatic one, and occurs in the zone of primary neutralization. The K-silicate alteration is formed by magmatic fluids with a high oxygen fugacity, high temperature, high aK+ and aMg2+. The upward superimposition of the K-silicate–sericitic alteration is related to the incorporation of meteoric fluids into magmatic fluids in an initial high oxygen fugacity environment and a high aMg2+. The quartz–sericitic alteration occurs from admixture of meteoric fluid into evolving magmatic fluids, with the predominance of the meteoric fluid, inducing an environment with a low aK+/aH+ ratio. The quartz–adularia–carbonate alteration is probably resulting of the admixture of a magmatic fluid with external and meteoric fluids, in an environment with high aK+. The propylitic alteration is observed only in the periphery zones of the deposit and clear relations with other alteration types were not observed.
Keywords:
porphyry-copper deposits, hydrothermal alterations, geochemistry, Elatsite
Pages:
17 - 42
Published online:
17 February 2026